Innervate can function as an increase to the target Spirit based mana regeneration by 400% and allows full mana regeneration while casting lasts for 20 seconds. I will share you with my thoughts and opinions on Innervate.
When to capture the use of innervate is totally up to you, but I recommend saving it until you over aggro or are in a pinch. In a 5 man, if you are mainly healer again I would save it until you need it, or if you are damaging save it until the healer is in a pinch and calls for it. Always be conscious of your 6 minute timer.
I was once in a raid with a resto druid healing and I was main puller, I just innervated everytime I needed mana and kept going. However, else wise I would have saved it. Thanks to the recent patch you may now cast while in moonkin form which saves me so much mana now.
When in a raid, count how many druids you have and then priests and pallies. Priests are typically your focus with pallies in second and yourself last, until you are a main healer. If we have an abundance of druids, we cycle as called. One of the main problems is double innervating a target. Though there are mods for this if you are like me and do not use mods, you need a different approach.
Here are the tips I use. First of all, know your healers. If priest X i constantly out of mana and his target frequently die, he is not a good candidate. If priest Y always has mana and doesn't have a problem keeping a tanks alive then he is your prime candidate. I will sit and watch a healer's play style for a few runs before deciding how to fit them in rotation.
We had a priest whom I will call H. H wasn't a good target because he could use up 3 innervates on a single short fight and he either entirely over healed one target or he let his assignments die frequently. H was removed from the innervate rotation unless we were dire.
We have a priest I call S. S is the best healer I have ever seen, he has excellent mana control, his targets never die and he rarely over heals. He could keep a 10 man alive by himself. He also regents fast on his own. He is my prime candidate and I try to always have one nerve in reserve for him at all times.
I innervate at 15% mana standard. We always set up innervates, either through a rotation or through an assignment. If we have very few druids (4 or less) it's on rotation as raid leader calls for it. If we have 5 or more (hey we had 8 one MC run) I assign by group to certain people. For example, druids 1 watch your group and group 2 for innervates, druid 2 watches your group and group 4, etc, etc. For certain people I assign a reserve for them alone, such as priest S. So I know that S will always have one when he needs it, plus we won't have two innervates wasted on one target.
Of course, no one receiving two innervates has ever complained. Once you make proper use of your timer, it will become an invaluable tool. Enjoy it.

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